Kinetics and mechanism of oxidation of aliphatic acetals with lead (IV) acetate
نویسنده
چکیده
The oxidative cleavage of aliphatic acetals of normal aliphatic aldehydes and substituted aliphatic aldehydes with aliphatic as well as aromatic alcohols with lead tetra acetate in acetic acid, aqueous acetic acid and in acetic acid-benzene medium is first order each in [oxidant] and [acetal] and yields the corresponding esters as the main product The rate of oxidation depends upon the dielectric constant of the medium, Stoichiometric investigations with different acetals indicated a I: I stoichiometry,
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